Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 137, Issue 9, Pages 3197-3200Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b00075
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Funding
- National Natural Science Foundation [21471126]
- National Thousand Plan Foundation
- 985 Program of the Chemistry and Chemical Engineering disciplines of Xiamen University (P.R. China)
- U.S. National Science Foundation [DMR-1308229]
- NIH [1S10RR026988]
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [1308229] Funding Source: National Science Foundation
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A simple and effective charge-assisted self-assembly process was developed to encapsulate a noble-metal-free polyoxometalate (POM) inside a porous and phosphorescent metalorganic framework (MOF) built from [Ru(bpy)(3)](2+)-derived dicarboxylate ligands and Zr-6(mu(3)-O)(4)(mu(3)-OH)(4) secondary building units. Hierarchical organization of photosensitizing and catalytic proton reduction components in such a POM@MOF assembly enables fast multielectron injection from the photoactive framework to the encapsulated redox-active POMs upon photoexcitation, leading to efficient visible-light-driven hydrogen production. Such a modular and tunable synthetic strategy should be applicable to the design of other multifunctional MOF materials with potential in many applications.
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