Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 137, Issue 38, Pages 12179-12182Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b04541
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Funding
- EPSRC [EP/K035274/1, EP/K014070/1, EP/K014668]
- CSC scholarship
- Engineering and Physical Sciences Research Council [EP/K014676/1, EP/C544838/1, EP/C544846/1, EP/K035274/1, EP/H046380/1] Funding Source: researchfish
- EPSRC [EP/K035274/1, EP/K014676/1, EP/H046380/1] Funding Source: UKRI
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Selective catalysis is used to prepare block copolyesters by combining ring-opening polymerization of lactones and ring-opening copolymerization of epoxides/anhydrides. By using a dizinc complex with mixtures of up to three different monomers and controlling the chemistry of the Zn-O(polymer chain) it is possible to select for a particular polymerization route and thereby control the composition of block copolyesters.
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