Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 137, Issue 30, Pages 9583-9586Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b06667
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- Heavy Element Chemistry Program of the Office of Basic Energy Sciences of the U.S. Department of Energy
- National Nuclear Security Administration of the Department of Energy [DE-AC52-06NA25396]
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The discovery that imido analogs Of actinyl dioxo cations can be extended beyond uranium into the transuranic elements is presented. Synthesis of the Np(V) Complex, Np(NDipp)(2)(tBu(2)bipy)(2)Cl (1), is achieved through treatment of a Np (IV) precursor with a bipyridine coligand and lithium-amide reagent. Complex 1 has been structurally characterized, analyzed by H-1 NMR and UV-vis-NIR spectroscopies, and the electronic structure evaluated by DFT calculations.
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