Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 137, Issue 4, Pages 1396-1399Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja512137t
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Funding
- U.S. Department of Energy, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering [DE-FG02-13ER46972]
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Metal-organic frameworks (MOFs) with the highest CO2 uptake capacity are usually those equipped with open metal sites. Here we seek alternative strategies and mechanisms for developing high-performance CO2 adsorbents. We demonstrate that through a ligand insertion pore space partition strategy, we can create crystalline porous materials (CPMs) with superior CO2 uptake capacity. Specifically, a new material, CPM-33b-Ni without any open metal sites, exhibits the CO2 uptake capacity comparable to MOF-74 with the same metal (Ni) at 298 K and 1 bar.
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