Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 137, Issue 50, Pages 15680-15683Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b11350
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Funding
- Inorganometallic Catalyst Design Center, an Energy Frontier Research Center, U.S. DOE [DE-SC0012702, DE-AC02-06CH11357]
- Institute for Catalysis in Energy Processes (U.S. DOE) [DE-FG02-03ER15457]
- MRSEC program at the Materials Research Center [NSF DMR-1121262]
- International Institute for Nanotechnology (IN)
- State of IL
- MRCAT member institutions
- U.S. DOE [DE-AC02-06CH11357, DE-AC0-06CH11357]
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A structurally well-defined mesoporous Hf-based metal organic framework (Hf-NU-1000) is employed as a well-defined scaffold for a highly electrophilic single-site d(0) Zr-benzyl catalytic center. This new material Hf-NU-1000-ZrBn is fully characterized by a variety of spectroscopic techniques and DFT computation. Hf-NU-1000-ZrBn is found to be a promising single-component catalyst (i.e., not requiring a catalyst/activator) for ethylene and stereoregular 1-hexene polymerization.
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