Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 137, Issue 17, Pages 5646-5649Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b02104
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Funding
- ERC
- DFG
- Erlangen DFG cluster of excellence EAM
- MIUR
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We introduce the use of pure molten orthophosphoric acid (o-H3PO4) as an electrolyte for self-organizing electrochemistry. This electrolyte allows for the formation of self-organized oxide architectures (one-dimensional nanotubes, nanochannels, nanopores) on metals such as tungsten that up to now were regarded as very difficult to grow self-ordered anodic oxide structures. In this work, we show particularly the fabrication of thick, vertically aligned tungsten oxide nanochannel layers, with pore diameter of ca. 10 nm and illustrate their potential use in some typical applications.
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