4.8 Article

Ligand-Enabled Cross-Coupling of C(sp3)-H Bonds with Arylsilanes

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 137, Issue 14, Pages 4618-4621

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b00890

Keywords

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Funding

  1. Scripps Research Institute
  2. NIH (NIGMS) [2R01GM084019]
  3. Sichuan University
  4. NSF under the Science Across Virtual Institutes program as part of the CCI Center for Selective C-H Functionalization [CHE-1205646]
  5. Grants-in-Aid for Scientific Research [15J04925] Funding Source: KAKEN
  6. Division Of Chemistry
  7. Direct For Mathematical & Physical Scien [1205646] Funding Source: National Science Foundation

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Pd(II)-catalyzed cross-coupling of C(sp(3))-H bonds with organosilicon coupling partners has been achieved for the first time. The use of a newly developed quinoline-based ligand is essential for the cross-coupling reactions to proceed.

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