Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 137, Issue 21, Pages 6738-6741Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b02946
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- University of Illinois at Chicago, Office of the Vice-Chancellor for Research
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The combination of Mo(CO)(6) and 10 Mol % of palladium acetate catalyzes the transformation of 2-nitroarenes to 3H-indoles through a tandem cyclization-[1,2] shift reaction of in situ generated nitrosoarenes. Mo(CO)(6) appears to have dual roles in this transformation generate generate CO and promote C-N bond formation to increase the yield of the N-heterocycle product.
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