Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2018, Issue 45, Pages 6355-6362Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201801201
Keywords
Diastereoselectivity; Ribofuranosides; Synthesis design; Thiols; Glycosylation
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Funding
- Toyota Riken Scholar Program
- Koshiyama Research Grant
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A method for the 1,2-cis-selective synthesis of 1-thio-alpha-ribofuranosides has been developed. Ribofuranosyl iodides as glycosyl donors react effectively with thiols under mild basic conditions to afford various 1-thio-alpha-ribofuranosides, including some that are unstable under acidic conditions.
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