Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2014, Issue 15, Pages 3127-3131Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201402022
Keywords
Nickel; Carbene ligands; Cross-coupling; Arenes; Amination; Sulfination
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Funding
- EPSRC
- ERC (Advanced Investigator Award FUNCAT)
- Engineering and Physical Sciences Research Council [GR/S31273/01] Funding Source: researchfish
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Two new [Ni(allyl)Cl(NHC)] complexes with the bulky yet flexible N-heterocyclic carbene (NHC) ligands IPr* {N,N-bis[2,6-bis(diphenylmethyl)-4-methylphenyl]imidazole-2-ylidene} and IPr*(OMe) {N,N-bis[2,6-bis(diphenylmethyl)-4-methoxyphenyl]imidazol-2-ylidene} are reported. These complexes were employed in the amination and sulfination of aryl halide species and were shown to perform well in these reactions, which typically required less than half as much catalyst as previous state-of-the-art nickel complexes.
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