Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2014, Issue 9, Pages 1823-1826Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201400031
Keywords
Carbon dioxide; Carbonates; Ionic liquids
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Funding
- Korea Research Foundation [2009-0094046, 2013008819]
- Korean Government, Ministry of Education, Science and Technology [Korea CCS R&D Center (KCRC)] [2012-0008935]
- National Research Foundation of Korea [2013R1A1A2008819, 2009-0094046] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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Diverse cyclic and acyclic carbonates such as ethylene carbonate, propylene carbonate, glycerol carbonate, and dimethyl carbonate were synthesized in moderate to good yields by the direct coupling of the corresponding alcohols with carbon dioxide in the absence of metal catalysts and inorganic bases. The direct carbonation mechanism of alcohols in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene, 1-butyl-3-methylimidazolium hexafluorophosphate, and dibromomethane was probed by O-18-labeling experiments and chiral alcohol experiments.
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