Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2015, Issue 3, Pages 638-646Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201403238
Keywords
Lactams; Nitrogen heterocycles; Amino acids; Organocatalysis; Synthetic methodology
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Funding
- National Research Foundation (South Africa)
- University of KwaZulu Natal
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The carbapenem (beta-lactam antibiotic) scaffold serves as a useful nucleophile in organocatalytic diarylprolinol trimethylsilyl ether mediated alpha-heterofunctionalization reactions leading to the formation of diverse products that bear multiple stereocenters in high diastereoselectivity and moderate to good yields.
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