Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2014, Issue 10, Pages 2032-2036Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201301833
Keywords
Synthetic methods; Radical reactions; Alkenes; Oxygen; beta-Keto sulfones
Categories
Funding
- Council of Scientific and Industrial Research (CSIR) [09/001(0379)/2013-EMR-I]
- Department of Science and Technology (DST) [SR/S1/OC-22/2010]
Ask authors/readers for more resources
beta-Keto sulfones were obtained in good to excellent yields (73-94%) directly from unactivated olefins by employing inexpensive sodium arenesulfinate salts as sulfonylating agents and K2S2O8 as a radical initiator in open flasks and aqueous media at room temperature under transition-metal-free conditions. The reported oxidative sulfonylation protocol is highly practical and environmentally benign, as self-manifested by the extremely mild reaction conditions.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available