Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2015, Issue 3, Pages 616-624Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201403354
Keywords
Synthetic methods; Oxidation; C-F bond functionalization; Fluorine; Nitriles; Ketones
Categories
Funding
- National Natural Science Foundation of China (NSFC) [21176222]
- Public Projects of Zhejiang Province [2014C31133]
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A highly efficient and simple procedure was developed to synthesize substituted fluorinated nitriles and diaryl ketones under mild conditions from polyfluorobenzenes and phenylacetonitriles. This coupling process was achieved by using a selective C-F bond functionalization without a transitionmetal catalyst. The reactions had good functional group tolerance and provided the products in moderate to excellent yields.
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