Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2014, Issue 36, Pages 8160-8166Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201403091
Keywords
Total synthesis; Natural products; Carbohydrates; Nucleosides; Glycosylation
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Funding
- Aristotle University of Thessaloniki [87852]
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The synthesis of marine nucleosides trachycladines A and B and two nucleoside analogues was accomplished following a versatile and high-yielding scheme starting from D-ribose. The key step involved a regio- and stereoselective direct Vorbruggen glycosylation reaction between the appropriate nucleobase and a common intermediate, 2-C-methyl-D-5-deoxyribofuranose triacetate.
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