4.5 Article

Synthesis and Characterization of cis-A2B-Type meso-Triaryl-Substituted Corroles

Journal

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2015, Issue 1, Pages 130-134

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201403217

Keywords

Synthetic methods; Porphyrinoids; Corroles; Cyclization; Cyclic voltammetry

Funding

  1. Japan Society for the Promotion of Science (JSPS KAKENHI) [25220802, 25620031, 20705446]

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A practical synthesis of cis-A(2)B-type 5,10,15-triarylcorroles has been developed that involves [2+2]-type acid-catalyzed condensation of 5-aryldipyrromethane and 5-(pentafluorophenyl)dipyrromethane-1-carbinol and subsequent 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) induced oxidative cyclization. All the corroles thus synthesized were structurally well-characterized, and their optical and electrochemical properties were also studied.

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