Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2014, Issue 12, Pages 2576-2583Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201400096
Keywords
Synthetic methods; Homogeneous catalysis; Palladium; Acylation; C-H bond activation; Arenes; Regioselectivity
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Funding
- National Natural Science Foundation of China (NSFC) [21272174]
- Key Projects of Shanghai in Biomedicine [08431902700]
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A highly efficient protocol for regioselective synthesis of diaryl ketones by palladium-catalyzed direct acylation of arenes using thioethers as directing groups is reported. The possible pathway of direct acylation between thioethers and -oxocarboxylic acids is discussed.
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