Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2014, Issue 21, Pages 4515-4522Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201402068
Keywords
Homogeneous catalysis; Gold; Hydroamination; Dinuclear complexes; Cooperative effects
Categories
Funding
- DFG [SFB/TRR 88]
- Helmholz-Research-School
- Deutsche Forschungsgemeinschaft (DFG)
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Mono- and dinuclear gold catalysts were investigated in the intermolecular hydroamidation of olefins. Upon activation of [Ph3PAuCl] and [xantphos(AuCl)(2)] with various silver salts (AgOTf, Ag[BF4], and Ag[SbF6]), diverging reactivity of the resulting cationic gold complexes was observed. It was found that both the binding ability of the counterion and the solvent have a significant impact on the reactivity of the mono-and dinuclear complexes.
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