Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2014, Issue 20, Pages 4381-4388Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201402202
Keywords
Synthetic methods; Asymmetric synthesis; Chiral auxiliaries; Cross-coupling; Amines
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Funding
- French Ministere de l'Enseignement Superieur et de la Recherche
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A new and concise method for the synthesis of enantioenriched 2-heteroaryl cyclic amines was developed through an intramolecular chirality transfer. The influence of the nature of both ring size and heteroaryl moiety was investigated. The versatility of this reaction was demonstrated by the enantioselective synthesis of (-)-anabasine.
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