Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2014, Issue 31, Pages 6846-6849Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201403024
Keywords
Homogeneous catalysis; Palladium; Phosphorus; Allylation; Enantioselectivity; Regioselectivity
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Funding
- National Natural Science Foundation of China (NSFC) [21272175]
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The enantioselective Pd-catalyzed allylation of diaryl-substituted allylic carbonates and diphenylphosphine oxide was investigated. This method gave allylic diphenylphosphine oxides in yields up to 95% with 97% ee. Pd-catalyzed allylation of (E)-methyl allyl carbonates with diisopropyl phosphonate was also examined.
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