Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2014, Issue 17, Pages 3570-3574Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201402199
Keywords
Oxygen heterocycles; Michael addition; Lewis acids; Domino reactions; Nucleophilic addition
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Funding
- Council of Scientific and Industrial Research (CSIR), New Delhi
- Department of Science and Technology (DST), New Delhi
- CSIR
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A Lewis acid catalyzed tandem nucleophilic addition/oxa-Michael reaction was developed for the synthesis of cis-2,6-disubstituted tetrahydropyran (THP) derivatives in good yields with excellent diastereoselectivities. The strategy was successfully used in the construction of THP derivatives with three stereocenters in a highly stereoselective fashion.
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