Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2013, Issue 28, Pages 6263-6266Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201300829
Keywords
Transition metals; Copper; Cesium; Boron; Lewis bases
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Funding
- National Natural Science Foundation of China (NSFC) [21172074]
- National Basic Research Program of China (973 Program) [2011CB808600]
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Herein we describe the unexpected borylation of aryl iodides promoted by a Cs2CO3 and MeOH system. This formal nucleophilic boryl substitution could be applied to a wide range of functionalized aryl iodide compounds. The preliminary results indicate that this process is neither copper catalyzed nor radical mediated.
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