Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2013, Issue 21, Pages 4490-4494Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201300626
Keywords
Organocatalysis; Immobilization; Supported catalysts; Michael addition; Flow chemistry
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Funding
- Hungarian Scientific Research Fund (OTKA) [K-69086]
- Lendulet Program [E-13/11/2010]
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This paper describes the preparation of highly efficient, easily accessible, and robust immobilized bifunctional organocatalysts. There was no need to employ any tether to secure high enantio- and diastereoselectivities in various Michael addition reactions. The synthetically useful Michael adducts were obtained within reasonable reaction times with the advantage of easy product isolation and the possibility of automation by using a flow chemistry apparatus.
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