Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2013, Issue 23, Pages 5106-5110Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201300361
Keywords
Synthetic methods; Homogeneous catalysis; Alcohols; Copper; Oxidation
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Funding
- University Grant Commission (UGC), India under UGC-SAP of the Institute of Chemical Technology (ICT), Matunga
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An efficient methodology has been developed for the synthesis of nitriles through an aerobic oxidative reaction of alcohols and ammonium formate with copper as a homogeneous catalyst under a normal air atmosphere and solvent-free conditions. This protocol uses the air as a green oxidant and ammonium formate as the nitrogen source. A wide range of substrates were well tolerated in the reaction that gave water as a byproduct.
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