Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2013, Issue 36, Pages 8094-8096Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201301329
Keywords
Asymmetric catalysis; Hypervalent compounds; Organocatalysis; Oxidation; Enantioselectivity
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Funding
- Centre National de la Recherche Scientifique (CNRS)
- Universite Joseph Fourier
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Original and readily available 3,3-diiodo-BINOL-fused maleimides were designed as hypervalent iodine(III) organocatalysts. They were used in intermolecular oxidation reactions at the -position of ketones. The expected products were obtained with yields and enantiomeric excesses that were comparable to the best reported values achieved using structurally different organocatalysts.
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