Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2014, Issue 3, Pages 616-623Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201301284
Keywords
Nitrogen heterocycles; Palladium; Carbonylation; Amines; Reaction mechanisms
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Funding
- Specialized Research Fund for the Doctoral Program of Higher Education [20120161110041]
- Hunan Provincial Natural Science Foundation of China [13JJ2018]
- National Natural Science Foundation of China [21172060]
- Fundamental Research Funds for the Central Universities (Hunan University) [2011-015]
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A new, mild route to access 3-methyleneindolin-2-ones is presented that proceeds through a room-temperature, palladium-catalyzed intramolecular oxidative aminocarbonylation of alkenes with amines and CO. This method represents a new aminocarbonylation strategy by employing an oxidative functionalization of a vinyl C(sp(2))-H bond.
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