Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2013, Issue 25, Pages 5574-5579Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201300694
Keywords
Fluorine; Selenium; Selenones; Oxygenation; Hypofluorous acid
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Funding
- Israel Science Foundation [373/13]
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A general route for the preparation of selenones (R2SeO2) is presented. This task is achieved through the quick and high-yielding reaction of selenides (R2Se) with HOF center dot CH3CN. The reaction tolerates some elusive electron-deficient and sterically hindered selenides. Some mechanistic aspects are also investigated and discussed.
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