Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2013, Issue 34, Pages 7688-7692Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201301248
Keywords
Oxidation; Coupling reactions; Reaction mechanisms; Selenium; C-H activation
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Funding
- University Grants Commission (UGC)
- Council of Scientific and Industrial Research (CSIR), New Delhi
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An oxidative coupling reaction between formamides and diselenides under metal-free conditions is described. The C-Se bond formation occurred exclusively at the carbonyl carbon by using aqueous tert-butyl hydroperoxide and 4 angstrom molecular sieves and the coupled products, selenocarbamates, were obtained in moderate-to-good yields.
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