Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2013, Issue 33, Pages 7583-7592Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201301004
Keywords
Synthetic methods; Hydroamination; Nitrogen heterocycles; Alkenes; Alkynes; Amines; Titanium
Categories
Funding
- Deutsche Forschungsgemeinschaft (DFG)
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A new (aminopyrimidinato)titanium complex has been synthesised from inexpensive and easily accessible 2-(tert-butylamino)pyrimidine and [Ti(NMe2)(4)] and used as a catalyst for the intermolecular hydroamination of alkynes as well as the cyclization of aminoalkenes. The hydroamination reactions of 1-phenylpropyne and terminal arylalkynes deliver the corresponding anti-Markovnikov addition products with excellent yields and regioselectivities.
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