Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2013, Issue 27, Pages 6021-6026Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201300909
Keywords
Iron; Nanoparticles; Benzoylation; Lewis acids; Heterogeneous catalysis
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Funding
- Department of Science and Technology (DST) [SR/WOS-A/CS-115/2011(G)]
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ortho-Benzoylation of phenols with aryl aldehydes to afford the substituted 2-hydroxybenzophenones can be catalyzed efficiently by Fe3O4 nanoparticles under ligand-free conditions. This method is useful for the preparation of xanthones in good yields. The catalyst can be magnetically removed and recycled easily over four cycles without a significant decrease in activity.
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