Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2013, Issue 7, Pages 1209-1213Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201201590
Keywords
Supramolecular chemistry; Host-guest systems; Receptors; Macrocycles; Pillararenes
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Funding
- National Natural Science Foundation of China (NSFC) [91027006, 21125417]
- Fundamental Research Funds for the Central Universities [2012QNA3013]
- Program for New Century Excellent Talents in University
- Zhejiang Provincial Natural Science Foundation of China [R4100009]
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A new pillar[5]arene-based heteroditopic receptor containing a urea anion recognition site was designed and made. It was demonstrated that the introduction of the urea group remarkably promoted the binding affinity to n-octyltriethylammonium salts with different counterions in chloroform, as the corresponding monotopic host, 1,4-dimethoxypillar-[5]arene, showed weak complexation with these guests. The important role of the urea unit was investigated and it was shown that the urea group and the macrocyclic unit not only provided positioned binding sites for the guests but also acted cooperatively in binding these guests.
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