Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2013, Issue 31, Pages 7083-7094Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201301087
Keywords
Synthesis design; Aldol reactions; Epoxidation; Diastereoselectivity; Terpenoids
Categories
Funding
- Nantes University
- PDL region
- Algerian-French fellowship: PROFAS B for a fellowship
- European Research Council (ERC) [278845 StG]
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We have developed an efficient diastereoselective synthetic route towards a nardosinane sesquiterpene scaffold. The strategy used a key bicyclic diene intermediate 11a, and allowed access to valuable polyoxygenated sesquiterpenes 21 and 22, which may be regarded as analogues of the natural sesquiterpenes laevinol B and fulvol acetate, respectively.
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