Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2013, Issue 27, Pages 6146-6151Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201300692
Keywords
Enantioselectivity; Amino alcohols; Diols; Ruthenium; Asymmetric catalysis
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Funding
- Yoshida Scholarship Foundation
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Enantioselective synthesis of -amino alcohols from 1,2-diols by the use of [RuCl2(p-cymene)](2)/(S,R)-JOSIPHOS catalysis was developed. Several 1,2-diols were treated with secondary amines to afford the corresponding optically active -amino alcohols in up to 99% yield with 77%ee.
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