Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2013, Issue 26, Pages 5814-5819Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201300932
Keywords
Asymmetric catalysis; Chirality; Silicon; Enzymes; Diols
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Funding
- National Natural Science Foundation of China (NSFC) [21173064, 21205025]
- Zhejiang Provincial Natural Science Foundation of China (ZPNSFC) [Q12B020037]
- Program for Excellent Young Teachers in Hangzhou Normal University (HNUEYT) [JTAS 2011-01-014]
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A series of silicon-containing diols are synthesized and used in lipase-catalyzed remote desymmetrization. This synthetic method is valuable in the construction of optically active silicon-stereogenic organosilicon compounds. Good enantioselectivities of the remote desymmetrization was achieved with Candida antarctica lipase B (CAL-B) (up to 90:10er).
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