Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2013, Issue 27, Pages 6108-6123Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201300508
Keywords
Cyclophanes; Ligand design; Nitrogen heterocycles; Asymmetric catalysis
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Funding
- Collaborative Research Center [SFB/TRR 88 3MET]
- Feasibility Study for Young Scientists (FYS)
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A novel family of [2.2]paracyclophane derivatives is described. Different substituted pyrazole, triazole and pyrimidine moieties were introduced to the [2.2]paracyclophane scaffold and the products were characterized spectroscopically and by X-ray structure analysis. These compounds are promising ligands for application in asymmetric catalysis. We show here that one of these ligands can catalyze asymmetric conjugate addition. Furthermore a palladium complex was synthesized by using a hydroxy-pyrazolyl[2.2]paracyclophane ligand.
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