Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2013, Issue 29, Pages 6694-6701Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201300890
Keywords
Asymmetric synthesis; Allylation; Reduction; Alkylation; Fluorine
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Funding
- Centre National de la Recherche Scientifique (CNRS)
- Conseil Regional Champagne-Ardenne
- Conseil General de la Marne
- EU-program Fundo Europeu de Desenvolvimento Regional (FEDER) for the PlAneT CPER project (Analytical platform)
- Senegalese Ministere de l'Enseignement Superieur
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The asymmetric synthesis of trifluoromethylated tertiary and secondary carbinamines (,-dibranched and -branched amines) was achieved by reaction of alkyl, aryl and allyl organomagnesium or organolithium reagents to trifluoromethyl N-tert-butanesulfinyl hemiaminals, bench-stable analogs of the corresponding ketoimines.
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