4.5 Article

Synthesis of α-Keto-1,2,3-triazoles Through Copper Iodide Catalyzed Oxygenation

Journal

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2014, Issue 3, Pages 654-659

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201301035

Keywords

Nitrogen heterocycles; C-H activation; Oxidation; Copper; Ketones

Funding

  1. Ministere de l'Enseignement et de la Recherche Scientifique
  2. Centre National de la Recherche Scientifique (CNRS)
  3. European Union (EU)
  4. Erasmus program, Germany, Greece

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Benzyltriazoles have been catalytically oxidized by using CuI and tert-butyl hydroperoxide to yield phenyl(1H-1,2,3-triazol-4-yl)methanone derivatives in good yields at room temperature.

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