Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2012, Issue 30, Pages 5902-5907Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201201003
Keywords
Host-guest systems; Pillar-arenes; Pseudorotaxanes; Macrocycles; Supramolecular chemistry
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Funding
- National Natural Science Foundation of China [20834004, 91027006, 21125417]
- Fundamental Research Funds for the Central Universities [2012QNA3013]
- Program for New Century Excellent Talents in University
- Zhejiang Provincial Natural Science Foundation of China [R4100009]
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Cavity-extended pillar[5]arenes containing electron-rich naphthyl groups have been demonstrated to have enhanced binding affinity to linear guests containing electron-deficient pyridinium units. The importance of size effect, charge density, cooperative effect, and C-H...pi interactions were investigated, and these factors play significant roles in the complexation of these hostguest systems.
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