Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2012, Issue 31, Pages 6140-6143Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201201191
Keywords
Alkynes; Oxygen heterocycles; Gold; Oxophilicity; Rearrangement
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Funding
- Ministerio de Economia y Competitividad (MI-NECO), Spain [CQT-201020517-C02]
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The gold(III)-catalyzed rearrangement of tetrasubstituted 1-alkynyloxiranes is described. This transformation led to a different reaction outcome with respect to related substrates previously studied. Thus, tertiary a-alkynylketones or alkynols can be selectively obtained. Moreover, gold(III) proved capable to catalyze the rearrangement of simple epoxides. These results indicate that gold(III) complexes act as oxophilic Lewis acids rather than p-acids in these transformations.
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