Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2012, Issue 6, Pages 1223-1229Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201101633
Keywords
Sensors; Chirality; Receptors; Boronic acid; Saccharides; Fluorescence
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Funding
- National Natural Science Foundation of China [20832001, 20972065, 21074054]
- National Basic Research Program of China [2007CB925103, 2010CB923303]
- University of Bath
- Royal Society (UK)
- National Natural Science Foundation of China (NSFC) (China-UK Cost-Share Science Networks) [21011130154]
- Dalian University of Technology
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Modular diboronic acid receptors R-1 and S-1 were synthesized and found to be selective fluorescent chemosensors for saccharides. The fluorescence intensity of R-1 and S-1 increased on addition of saccharides due to the formation of intramolecular 1:1 cyclic complexes. In general, R-1 has higher binding constants and produces a higher fluorescent response with saccharides than S-1.
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