Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2012, Issue 18, Pages 3416-3423Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201200194
Keywords
Etherification; Friedel-Crafts alkylation; Polycycles; Supramolecular chemistry; Synthetic methods
Categories
Funding
- Deutsche Forschungsgemeinschaft (DFG) [KU 663/16-1]
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The synthesis and characterization of several C3v-symmetrically extended tribenzotriquinacenes (TBTQs) bearing six benzylic C1-tentacular functional groups at the arene periphery were reported. A new C3v-symmetrical hexakis(chloromethyl)-substituted TBTQ derivative was used as the key intermediate, and other derivatives were synthesized with high efficiency by either sixfold nucleophilic substitution reactions with phenols or sixfold Friedel-Crafts alkylation reactions with various arenes.
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