Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2011, Issue 20-21, Pages 3671-3674Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201100231
Keywords
Calcium; Silanes; Direct substitution; Alcohols; C-C coupling
Categories
Ask authors/readers for more resources
A calcium-catalyzed direct substitution of pi-activated alcohols with different organosilanes under very mild reaction conditions is presented. The high reactivity of the calcium catalyst allows efficient conversion of secondary and tertiary allylic, secondary benzylic, and tertiary propargylic alcohols with allyltrimethylsilane at room temperature. Furthermore, the first direct substitution of an alcohol with (E)- as well as (Z)-alkenylsilanes was achieved under mild reaction conditions.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available