Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2012, Issue 8, Pages 1471-1493Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201101489
Keywords
Kinetic resolution; Acylation; Amines; Amides
Categories
Funding
- Russian Foundation for Basic Research [10-03-00084]
- State Program for Supporting of Leading Scientific Schools of the Russian Federation [65261.2010.3]
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Acylative kinetic resolution of racemic amines occupies a highly important place among the methods for preparation of enantio enriched or pure amines. Nonenzymatic acylative kinetic resolution is usually carried out in the presence of chiral acyl-transfer catalysts or under the action of chiral enantio- or diastereoselective resolving agents. Recently, this line of investigations has been rapidly developed and very interesting results of design and synthetic application of both new catalysts and chiral acylating agents have been obtained. This microreview summarizes the recent advances in this area.
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