Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2011, Issue 5, Pages 831-841Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201001558
Keywords
Fluorine; Silicon; Amines; Schiff bases; Nucleophilic trifluoromethylation
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Funding
- Russian Foundation for Basic Research [08-03-00428]
- Russian Academy of Sciences [7]
- Ministry of Science [02.740.11.0258]
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The review covers nucleophilic addition reactions of the CF3 carbanion to C=N bonds. Trifluoromethylation reactions of imines, nitrones, hydrazones, iminium ions and azomethine ylides are discussed. Various trifluorometylating reagents are considered, among which the major emphasis is placed on reactions using the Ruppert-Prakash reagent.
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