Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2011, Issue 24, Pages 4536-4539Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201100683
Keywords
Asymmetric catalysis; Organocatalysis; Friedel-Crafts reactions; Fluoroalkylation; Enantioselectivity
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Funding
- Chinese Academy of Sciences
- National Natural Science Foundation [20972179, 21032006]
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The enantioselective Friedel Crafts fluoroalkylation of indoles with fluoroalkylated nitroalkenes, catalyzed by chiral phosphoric acid is described. The regioselectivity of fluoroalkylated nitroalkenes is a problem worth discussing, and it was found that the carbon atom adjacent to the fluoroalkyl group is more reactive than that adjacent to NO2 group.
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