Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2011, Issue 11, Pages 2035-2038Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201001745
Keywords
Nitrosoarenes; Alkynes; Nitrogen heterocycles; Copper; Deoxygenation
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Funding
- Louisiana Board of Regents [LEQSF(2009-12)-RD-B-08]
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A direct method for the preparation of various 3-arylindoles from their corresponding nitrosoarenes has been developed. Various substituted nitrosoarenes and alkynes were employed to obtain substituted indoles by using a Cu-II-Cu-0 catalytic system. This is a two-step method that involves annulation of the nitrosoarene and alkyne followed by deoxygenation to give 3-arylindoles.
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