Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2011, Issue 20-21, Pages 3719-3722Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201100291
Keywords
Alkynes; Carbenoids; Cyclopropanation; Diastereoselectivity; Gold
Categories
Funding
- Norwegian Research Council
Ask authors/readers for more resources
A gold-catalyzed olefin cyclopropanation reaction of propargyl esters with vinyl ester or vinyl sulfonamide derivatives was investigated for the synthesis of highly substituted cyclopropane derivatives in good diastereoselectivity. By varying the vinyl species, trans-cyclopentenyl esters were selectively formed by a formal [3+2] cycloaddition.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
