Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2011, Issue 30, Pages 5971-5980Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201100745
Keywords
Synthesis design; Zinc; Nickel; Palladium; UV/Vis spectroscopy; N,O ligands
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Funding
- The Deutsche Forschungsgemeinschaft [MA4061/4-1]
- Fonds der Chemischen Industrie
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The synthesis of two novel tetrakis(salicylaldehydes) based on a rigid tetraphenylmethane core is presented. These salicylaldehydes were used as precursors for the construction of three-dimensional multimetallic salphens, as exemplified by the synthesis of rigid and shape-persistent tetranuclear zinc-, nickel- and palladium-salphens with defined geometries and distances between the metal sites. The UV/Vis measurements of the tetranuclear metal complexes are presented.
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