Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2011, Issue 8, Pages 1520-1526Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201001492
Keywords
Sulfur; Hydrazones; Iron; Cross-coupling; Diazo compounds; Carbenes
Categories
Funding
- Direccion General de Investigacion (DGI) of Spain [CTQ2007-61048/BQU]
- Consejeria de Educacion y Ciencia of Principado de Asturias [IB08-088]
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The Fe-catalyzed decomposition of sulfonylhydrazones gives rise to sulfones. The reaction is quite general and allows the preparation of sulfones from a variety of aryl, alkyl, and a, alpha,beta-unsaturated aldehydes and ketones. Crossover experiments reveal that the reaction is an intermolecular process, which may proceed by nucleophilic attack of the sulfinate anion on an iron carbene complex.
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