Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2011, Issue 16, Pages 3001-3008Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201100061
Keywords
Alkaloids; Chlorination; Enantioselectivity; Organocatalysis; Synthetic methods
Categories
Funding
- National Natural Science Foundation of China [20772030, 21072056]
- Fundamental Research Funds for the Central Universities
- Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry
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O-Benzoylquinidine is an effective organocatalyst for the asymmetric chlorination of 3-aryloxindoles by using easily available N-chlorosuccinimide (NCS) as chlorine source to give the corresponding 3-aryl-3-chlorooxindoles in excellent yields and up to 93% enantiomeric excess.
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